The key cyclization of an allylic alkoxyl radical to a carbon-centered allylic radical had been detected earlier (3) and has subsequently been recognized as a "key step in hydroperoxide-amplified ...

Nature Chemistry: “Metalloradical approach for concurrent control in intermolecular radical allylic C−H amination" DOI: 10.1038/s41557-022-01119-4 ...

In recent research 4 we have observed a case of true electromerism in a pair of organic radical cations containing two allylic moieties. The two electromers distinguish themselves by the nature of ...