The aim of this research was to develop high speed microwave assisted Negishi cross coupling reaction starting from arylchlorides and to extend Fu's catalytic system (Netherton, M. R.; Fu, G. C. Org.

Negishi cross-coupling reactions have been widely used to form C-C bonds since the 1970s and are often perceived as the result of two metals (i.e zinc and palladium/nickel) working in synergy.

In 1977, he reported the reaction that later became known as the Negishi Coupling, which uses a palladium catalyst to couple asymmetrical carbon-carbon compounds in high yields (Chem. Comm. 1977 ...

Traditionally, chemists have synthesized biaryl bonds using metal-catalyzed reactions, such as Suzuki and Negishi cross-couplings. However robust, these processes require additional ...

Ei-ichi Negishi started award-winning chemistry research while at SU in the 1970s. ... Negishi developed the so-called “Negishi Coupling,” a complex cross-coupling reaction in organic chemistry.

Discovery of new reactions-1) Pd-catalyzed cross-coupling reactions of organometals known as the Negishi coupling (listed in Merck Index, 13th Ed.), 2) first Pd-catalyzed cross-coupling of ...

Some of the most recent and significant developments in homogeneous nickel catalysis are reviewed, including nickel-mediated cross-coupling reactions and carbon–hydrogen bond activation reactions.

The 2010 Nobel Prize in Chemistry has been awarded to Richard F. Heck, Ei-ichi Negishi and Akira Suzuki for developing palladium-catalyzed cross coupling. This chemical tool has vastly improved ...

Negishi, the Herbert C. Brown Distinguished Professor and Teijin Limited Director of the Negishi-Brown Institute, won the 2010 Nobel Prize in chemistry for his palladium-catalyzed cross coupling ...